| Celtic (Glasgow) FC v Villarreal CF 08/04/2004 | £5.50 | |
| Everton FC v Villarreal CF 09/08/2005 | £4.60 | |
| Rangers (Glasgow) FC v Villarreal CF 22/02/2006 | £4.70 | |
| West Ham United FC v Villarreal CF 09/08/2008 | £9.99 | |
| Celtic (Glasgow) FC v Villarreal CF 10/12/2008 | £5.50 | |
| Arsenal FC v Villarreal CF 15/04/2009 | £4.80 | |
| Tottenham Hotspur FC v Villarreal CF 29/07/2010 | £7.50 | |
| Manchester City FC v Villarreal CF 18/10/2011 | £6.00 | |
| Liverpool FC v Villarreal CF 05/05/2016 | £6.50 | |
| Leicester City FC v Villarreal CF 04/08/2021 | £7.50 | |
| Chelsea FC v Villarreal CF 11/08/2021 | £14.99 | |
| Manchester United FC v Villarreal CF 29/09/2021 | £7.50 |