| Celtic (Glasgow) FC v Villarreal CF 08/04/2004 | £5.50 | |
| Valencia CF v Villarreal CF 06/05/2004 | View match | |
| Everton FC v Villarreal CF 09/08/2005 | £4.60 | |
| Manchester United FC v Villarreal CF 22/11/2005 | View match | |
| Rangers (Glasgow) FC v Villarreal CF 22/02/2006 | £4.70 | |
| Arsenal FC v Villarreal CF 19/04/2006 | £7.50 | |
| West Ham United FC v Villarreal CF 09/08/2008 | £9.99 | |
| Manchester United FC v Villarreal CF 17/09/2008 | View match | |
| Celtic (Glasgow) FC v Villarreal CF 10/12/2008 | £5.50 | |
| Arsenal FC v Villarreal CF 15/04/2009 | £4.80 | |
| Tottenham Hotspur FC v Villarreal CF 29/07/2010 | £7.50 | |
| Tottenham Hotspur FC v Villarreal CF 29/07/2010 | £6.50 |