| Motherwell FC v Dunfermline Athletic 27/08/1966 | View match | |
| Falkirk FC v Motherwell FC 31/08/1966 | View match | |
| Partick Thistle FC v Motherwell FC 03/09/1966 | View match | |
| Airdrieonians (Old) v Motherwell FC 10/09/1966 | View match | |
| Motherwell FC v Stirling Albion FC 17/09/1966 | View match | |
| St Mirren FC v Motherwell FC 24/09/1966 | View match | |
| Motherwell FC v Hibernian FC 01/10/1966 | View match | |
| Clyde v Motherwell FC 08/10/1966 | View match | |
| Motherwell FC v St Johnstone FC 15/10/1966 | View match | |
| Dundee v Motherwell FC 22/10/1966 | View match | |
| Motherwell FC v Ayr United FC 29/10/1966 | View match | |
| Rangers (Glasgow) FC v Motherwell FC 05/11/1966 | View match |